Information card for entry 7029122

Structure parameters

• Common name: μ-dichlorobis{(hydrogenbis(diphenylphosphinito-K1P)(ethanoyl-K1C)rhodium(III)}
• Chemical name: μ-dichlorobis{(hydrogenbis(diphenylphosphinito-K1P)(ethanoyl-K1C)rhodium(III)}
• Formula: C61 H60 Cl2 O6 P4 Rh2
• Calculated formula: C61 H60 Cl2 O6 P4 Rh2
• Title of publication: Mixed anhydride complexes of rhodium(i) and ruthenium(ii) - their synthesis and ligand rearrangements.
• Authors of publication: Coetzee, Jacorien; Eastham, Graham R.; Slawin, Alexandra M. Z.; Cole-Hamilton, David J
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 9
• Pages of publication: 3479 - 3491
• a: 20.089 ± 0.007 Å
• b: 12.811 ± 0.005 Å
• c: 22.725 ± 0.008 Å
• α: 90°
• β: 101.12 ± 0.005°
• γ: 90°
• Cell volume: 5739 ± 4 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0336
• Residual factor for significantly intense reflections: 0.0318
• Weighted residual factors for significantly intense reflections: 0.0814
• Weighted residual factors for all reflections included in the refinement: 0.0836
• Goodness-of-fit parameter for all reflections included in the refinement: 0.968
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No