Information card for entry 7030861

Structure parameters

• Formula: C31 H15 Au Co5 O12 P
• Calculated formula: C31 H15 Au Co5 O12 P
• SMILES: [Au]12([Co]3456([Co]7891([Co]1%10%11([Co]%1237([Co]41([C]258%10%12)(C#[O])(C%11=O)C#[O])(C9=O)(C6=O)C#[O])(C#[O])C#[O])(C#[O])C#[O])(C#[O])C#[O])[P](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Homoleptic and heteroleptic Au(i) complexes containing the new [Co5C(CO)12](-) cluster as ligand.
• Authors of publication: Bortoluzzi, Marco; Ciabatti, Iacopo; Femoni, Cristina; Funaioli, Tiziana; Hayatifar, Mohammad; Iapalucci, Maria Carmela; Longoni, Giuliano; Zacchini, Stefano
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 25
• Pages of publication: 9633 - 9646
• a: 12.887 ± 0.005 Å
• b: 23.816 ± 0.01 Å
• c: 12.612 ± 0.005 Å
• α: 90°
• β: 116.501 ± 0.005°
• γ: 90°
• Cell volume: 3464 ± 2 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 295 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1386
• Residual factor for significantly intense reflections: 0.1099
• Weighted residual factors for significantly intense reflections: 0.2911
• Weighted residual factors for all reflections included in the refinement: 0.3252
• Goodness-of-fit parameter for all reflections included in the refinement: 1.194
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No