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Information card for entry 7031296
Preview
Coordinates | 7031296.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C98 H75 Cl9 N6 Pd2 |
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Calculated formula | C98 H75 Cl9 N6 Pd2 |
Title of publication | Directional properties of fluorenylidene moieties in unsymmetrically substituted N-heterocyclic carbenes. Unexpected CH activation of a methylfluorenyl group with palladium. Use in palladium catalysed Suzuki-Miyaura cross coupling of aryl chlorides. |
Authors of publication | Teci, Matthieu; Brenner, Eric; Matt, Dominique; Gourlaouen, Christophe; Toupet, Loïc |
Journal of publication | Dalton transactions (Cambridge, England : 2003) |
Year of publication | 2014 |
Journal volume | 43 |
Journal issue | 32 |
Pages of publication | 12251 - 12262 |
a | 20.5938 ± 0.0005 Å |
b | 18.5018 ± 0.0004 Å |
c | 24.0322 ± 0.0007 Å |
α | 90° |
β | 103.048 ± 0.003° |
γ | 90° |
Cell volume | 8920.4 ± 0.4 Å3 |
Cell temperature | 150 ± 2 K |
Ambient diffraction temperature | 150 ± 2 K |
Number of distinct elements | 5 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.1384 |
Residual factor for significantly intense reflections | 0.0673 |
Weighted residual factors for significantly intense reflections | 0.1883 |
Weighted residual factors for all reflections included in the refinement | 0.2091 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.717 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | No |
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The link is: https://www.crystallography.net/7031296.html
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