Information card for entry 7031334

Structure parameters

• Chemical name: (4-fluoroaniline-κ<i>N</i>)[2-(pyridin-2-yl-κ<i>N</i>)phenyl-κ<i>C</i>^1^][2,4,6-tris(trifluoromethyl)phenyl]gold(+) trifluoromethanesulfonate(-) dichloromethane solvate 1/1/0.1
• Formula: C27.1 H16.2 Au Cl0.2 F13 N2 O3 S
• Calculated formula: C27.1 H16.2 Au Cl0.2 F13 N2 O3 S
• Title of publication: Luminescent monocyclometalated cationic gold(iii) complexes: synthesis, photophysical characterization and catalytic investigations.
• Authors of publication: Zehnder, Thomas N.; Blacque, Olivier; Venkatesan, Koushik
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 31
• Pages of publication: 11959 - 11972
• a: 10.0798 ± 0.0002 Å
• b: 12.6213 ± 0.0003 Å
• c: 12.7654 ± 0.0003 Å
• α: 94.426 ± 0.002°
• β: 110.35 ± 0.002°
• γ: 93.672 ± 0.002°
• Cell volume: 1510.92 ± 0.06 ų
• Cell temperature: 183 ± 2 K
• Ambient diffraction temperature: 183 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0292
• Residual factor for significantly intense reflections: 0.0245
• Weighted residual factors for significantly intense reflections: 0.0541
• Weighted residual factors for all reflections included in the refinement: 0.0565
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No