Information card for entry 7032056

Structure parameters

• Common name: Rh(Cp*)(N3)2(PPh3)
• Chemical name: Rh(Cp*)(N3)2(PPh3)
• Formula: C28 H30 N6 P Rh
• Calculated formula: C28 H30 N6 P Rh
• SMILES: [Rh]1234([P](c5ccccc5)(c5ccccc5)c5ccccc5)(N=N#N)(N=N#N)[c]5([c]4([c]3([c]2([c]15C)C)C)C)C
• Title of publication: Picosecond time-resolved infrared spectroscopy of rhodium and iridium azides.
• Authors of publication: Portius, Peter; Meijer, Anthony J. H. M.; Towrie, Michael; Crozier, Benjamin F.; Schiager, Ingrid
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 47
• Pages of publication: 17694 - 17702
• a: 17.62 ± 0.004 Å
• b: 8.6155 ± 0.0017 Å
• c: 17.542 ± 0.004 Å
• α: 90°
• β: 98.87 ± 0.03°
• γ: 90°
• Cell volume: 2631.1 ± 1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.09
• Residual factor for significantly intense reflections: 0.0457
• Weighted residual factors for significantly intense reflections: 0.0874
• Weighted residual factors for all reflections included in the refinement: 0.1015
• Goodness-of-fit parameter for all reflections included in the refinement: 0.994
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No