Information card for entry 7032815

Structure parameters

• Formula: C18 H32 F6 P Sb Se
• Calculated formula: C18 H32 F6 P Sb Se
• SMILES: [Sb](F)(F)(F)(F)(F)[F-].[P+](C(C)(C)C)(C(C)(C)C)(C(C)(C)C)[Se]c1ccccc1
• Title of publication: Evidence for a SN2-type pathway in the exchange of phosphines at a [PhSe]+ centre.
• Authors of publication: Forfar, Laura C.; Green, Michael; Haddow, Mairi F.; Hussein, Sharifa; Lynam, Jason M.; Slattery, John M.; Russell, Christopher A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 1
• Pages of publication: 110 - 118
• a: 8.4039 ± 0.0003 Å
• b: 15.0539 ± 0.0005 Å
• c: 35.2907 ± 0.0011 Å
• α: 90°
• β: 90.01°
• γ: 90°
• Cell volume: 4464.7 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0244
• Residual factor for significantly intense reflections: 0.0231
• Weighted residual factors for significantly intense reflections: 0.0615
• Weighted residual factors for all reflections included in the refinement: 0.0621
• Goodness-of-fit parameter for all reflections included in the refinement: 1.219
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No