Information card for entry 7033189

Structure parameters

• Formula: C28 H35.5 N1.5 Na O4.5 Rh S
• Calculated formula: C28 H29 N1.5 Na O4.5 Rh S
• Title of publication: Recoverable and recyclable water-soluble sulphonated salicylaldimine Rh(I) complexes for 1-octene hydroformylation in aqueous biphasic media.
• Authors of publication: Matsinha, Leah C.; Mapolie, Selwyn F.; Smith, Gregory S.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 3
• Pages of publication: 1240 - 1248
• a: 31.483 ± 0.003 Å
• b: 20.15 ± 0.0017 Å
• c: 10.3174 ± 0.0008 Å
• α: 90°
• β: 106.166 ± 0.002°
• γ: 90°
• Cell volume: 6286.4 ± 0.9 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1186
• Residual factor for significantly intense reflections: 0.0555
• Weighted residual factors for significantly intense reflections: 0.1371
• Weighted residual factors for all reflections included in the refinement: 0.1657
• Goodness-of-fit parameter for all reflections included in the refinement: 0.988
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No