Information card for entry 7033629

Structure parameters

• Common name: 14175b
• Chemical name: W(CO)3{6-(PhBP3)Mn(CO)3}
• Formula: C51 H41 B Mn O6 P3 W
• Calculated formula: C51 H41 B Mn O6 P3 W
• Title of publication: Group VI metal complexes of tris(diphenylphosphinomethyl)phenylborate: modulation of ligand donation via coordination of M(CO)3 units at the borate phenyl substituent.
• Authors of publication: Fischer, Paul J.; Weberg, Alexander B.; Bohrmann, Trent D.; Xu, Hanyue; Young, Victor G.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 8
• Pages of publication: 3737 - 3744
• a: 12.9471 ± 0.0011 Å
• b: 25.023 ± 0.002 Å
• c: 17.8217 ± 0.0015 Å
• α: 90°
• β: 110.161 ± 0.001°
• γ: 90°
• Cell volume: 5420 ± 0.8 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0435
• Residual factor for significantly intense reflections: 0.0383
• Weighted residual factors for significantly intense reflections: 0.0788
• Weighted residual factors for all reflections included in the refinement: 0.0803
• Goodness-of-fit parameter for all reflections included in the refinement: 1.139
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No