Information card for entry 7033631

Structure parameters

• Common name: [V2(PS3)2(mu-Se2)(mu-Se)][PPh4]2
• Formula: C91 H72 N3 O0.25 P4 S6 Se3 V2
• Calculated formula: C91 H72 N3 O0.25 P4 S6 Se3 V2
• Title of publication: Non-oxido divanadium(iv) and divanadium(v) thiolate complexes with a new type of chalcogenide bridging motif.
• Authors of publication: Wu, Hong-Ming; Chang, Ya-Ho; Tsai, Yi-Fang; Hsu, Kuei-Fang; Lee, Gene-Hsiang; Hsu, Hua-Fen
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 10
• Pages of publication: 4468 - 4473
• a: 23.551 ± 0.019 Å
• b: 13.683 ± 0.011 Å
• c: 27.38 ± 0.02 Å
• α: 90°
• β: 99.212 ± 0.014°
• γ: 90°
• Cell volume: 8709 ± 12 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 13
• Hermann-Mauguin space group symbol: P 1 2/c 1
• Hall space group symbol: -P 2yc
• Residual factor for all reflections: 0.1348
• Residual factor for significantly intense reflections: 0.0578
• Weighted residual factors for significantly intense reflections: 0.132
• Weighted residual factors for all reflections included in the refinement: 0.184
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No