Information card for entry 7034040

Structure parameters

• Formula: C35 H42 F6 N7 O2.5 P Ru
• Calculated formula: C35 H42 F6 N7 O2.5 P Ru
• Title of publication: Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation.
• Authors of publication: Arikawa, Yasuhiro; Nakamura, Takuo; Ogushi, Shinji; Eguchi, Kazushige; Umakoshi, Keisuke
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 12
• Pages of publication: 5303 - 5305
• a: 10.495 ± 0.003 Å
• b: 12.179 ± 0.004 Å
• c: 15.393 ± 0.005 Å
• α: 83.468 ± 0.009°
• β: 85.291 ± 0.011°
• γ: 79.745 ± 0.01°
• Cell volume: 1919.7 ± 1 ų
• Cell temperature: 93 K
• Ambient diffraction temperature: 93 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.06
• Weighted residual factors for all reflections included in the refinement: 0.1463
• Goodness-of-fit parameter for all reflections included in the refinement: 1.06
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No