Information card for entry 7034882

Structure parameters

• Formula: C30 H64 O2 P4 Rh2
• Calculated formula: C30 H64 O2 P4 Rh2
• SMILES: C1C[P](C(C)C)(C(C)C)[Rh]23(C(=O)[Rh]43(C2=O)[P](CC[P]4(C(C)C)C(C)C)(C(C)C)C(C)C)[P]1(C(C)C)C(C)C
• Title of publication: Synthesis and structure of rhodium(i) silyl carbonyl complexes: photochemical C-F and C-H bond activation of fluorinated aromatic compounds.
• Authors of publication: Zámostná, Lada; Sander, Stefan; Braun, Thomas; Laubenstein, Reik; Braun, Beatrice; Herrmann, Roy; Kläring, Paul
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 20
• Pages of publication: 9450 - 9469
• a: 16.2527 ± 0.0005 Å
• b: 12.6551 ± 0.0004 Å
• c: 35.9245 ± 0.0012 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7388.9 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0859
• Residual factor for significantly intense reflections: 0.0486
• Weighted residual factors for significantly intense reflections: 0.0783
• Weighted residual factors for all reflections included in the refinement: 0.0861
• Goodness-of-fit parameter for all reflections included in the refinement: 1.105
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No