Information card for entry 7035010

Structure parameters

• Formula: C38 H16 Cu F26 N2 P3
• Calculated formula: C38 H16 Cu F26 N2 P3
• SMILES: [Cu]12([P](c3c(F)c(F)c(F)c(F)c3F)(c3c(F)c(F)c(F)c(F)c3F)CC[P]1(c1c(F)c(F)c(F)c(F)c1F)c1c(F)c(F)c(F)c(F)c1F)[n]1c(c3[n]2c(C)ccc3)cccc1C.[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Long-lived and oxygen-responsive photoluminescence in the solid state of copper(i) complexes bearing fluorinated diphosphine and bipyridine ligands.
• Authors of publication: Nishikawa, Michihiro; Wakita, Yuri; Nishi, Tatsuya; Miura, Takumi; Tsubomura, Taro
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 19
• Pages of publication: 9170 - 9181
• a: 11.7046 ± 0.0019 Å
• b: 11.9986 ± 0.0018 Å
• c: 15.584 ± 0.002 Å
• α: 91.946 ± 0.007°
• β: 96.639 ± 0.007°
• γ: 101.608 ± 0.007°
• Cell volume: 2125.8 ± 0.5 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0976
• Residual factor for significantly intense reflections: 0.074
• Weighted residual factors for all reflections included in the refinement: 0.2108
• Goodness-of-fit parameter for all reflections included in the refinement: 1.083
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No