Information card for entry 7035535

Structure parameters

• Chemical name: pyridinium trans-difluoridotetrakis(pyridine)vanadium(III)hexafluorosilicate
• Formula: C25 H26 F8 N5 Si V
• Calculated formula: C25 H26 F8 N5 Si V
• Title of publication: Ternary transition-metal fluoride precursors for the fluorolytic sol-gel route: new insights into speciation and decomposition.
• Authors of publication: Kohl, J.; Wiedemann, D.; Troyanov, S. I.; Palamidis, E.; Lerch, M.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 29
• Pages of publication: 13272 - 13281
• a: 10.8047 ± 0.0002 Å
• b: 10.8047 ± 0.0002 Å
• c: 12.6865 ± 0.0004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1481.04 ± 0.06 ų
• Cell temperature: 149.9 ± 1 K
• Ambient diffraction temperature: 149.9 ± 1 K
• Number of distinct elements: 6
• Space group number: 127
• Hermann-Mauguin space group symbol: P 4/m b m
• Hall space group symbol: -P 4 2ab
• Residual factor for all reflections: 0.1004
• Residual factor for significantly intense reflections: 0.0508
• Weighted residual factors for significantly intense reflections: 0.1201
• Weighted residual factors for all reflections included in the refinement: 0.1325
• Goodness-of-fit parameter for all reflections included in the refinement: 0.844
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No