Information card for entry 7035921

Structure parameters

• Formula: C39 H48 Cl5 N4 O Rh
• Calculated formula: C39 H48 Cl5 N4 O Rh
• Title of publication: Characterization of a Rh(iii) porphyrin-CO complex: its structure and reactivity with an electron acceptor.
• Authors of publication: Yamazaki, Shin-Ichi; Yao, Masaru; Asahi, Masafumi; Sato, Hiroyasu; Yamano, Akihito; Ioroi, Tsutomu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 31
• Pages of publication: 13823 - 13827
• a: 12.62 ± 0.003 Å
• b: 8.246 ± 0.002 Å
• c: 19.435 ± 0.005 Å
• α: 90°
• β: 100.522 ± 0.004°
• γ: 90°
• Cell volume: 1988.5 ± 0.8 ų
• Cell temperature: 93 K
• Ambient diffraction temperature: 93 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0976
• Residual factor for significantly intense reflections: 0.0798
• Weighted residual factors for significantly intense reflections: 0.1531
• Weighted residual factors for all reflections included in the refinement: 0.1616
• Goodness-of-fit parameter for all reflections included in the refinement: 1.174
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No