Information card for entry 7036092

Structure parameters

• Formula: C32 H76 N2 Na2 O2 Si4
• Calculated formula: C32 H76 N2 Na2 O2 Si4
• SMILES: C(C)(C)(C)[Si](C)(C)[N]1([Si](C(C)(C)C)(C)C)[Na]([N]([Si](C(C)(C)C)(C)C)([Si](C(C)(C)C)(C)C)[Na]1[O]1CCCC1)[O]1CCCC1
• Title of publication: Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
• Authors of publication: Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 14
• Pages of publication: 6004 - 6014
• a: 15.833 ± 0.0008 Å
• b: 11.7764 ± 0.0006 Å
• c: 22.7974 ± 0.001 Å
• α: 90°
• β: 93.418 ± 0.005°
• γ: 90°
• Cell volume: 4243.1 ± 0.4 ų
• Cell temperature: 150.01 ± 0.1 K
• Ambient diffraction temperature: 150.01 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1056
• Residual factor for significantly intense reflections: 0.0642
• Weighted residual factors for significantly intense reflections: 0.1408
• Weighted residual factors for all reflections included in the refinement: 0.1656
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No