Information card for entry 7036098

Structure parameters

• Formula: C38 H90 Mg2 N2 Si4
• Calculated formula: C38 H90 Mg2 N2 Si4
• SMILES: C(C)(C)[Si](C(C)C)(C(C)C)N([Si](C(C)C)(C(C)C)C(C)C)[Mg]1[CH3][Mg]([CH3]1)N([Si](C(C)C)(C(C)C)C(C)C)[Si](C(C)C)(C(C)C)C(C)C
• Title of publication: Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
• Authors of publication: Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 14
• Pages of publication: 6004 - 6014
• a: 9.0592 ± 0.0009 Å
• b: 10.5786 ± 0.0009 Å
• c: 14.0661 ± 0.0013 Å
• α: 104.507 ± 0.007°
• β: 94.56 ± 0.008°
• γ: 114.542 ± 0.008°
• Cell volume: 1161.1 ± 0.2 ų
• Cell temperature: 150.01 ± 0.1 K
• Ambient diffraction temperature: 150.01 ± 0.1 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0963
• Residual factor for significantly intense reflections: 0.0585
• Weighted residual factors for significantly intense reflections: 0.1048
• Weighted residual factors for all reflections included in the refinement: 0.1181
• Goodness-of-fit parameter for all reflections included in the refinement: 1.022
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No