Information card for entry 7036127

Structure parameters

• Chemical name: bicyclo[2.2.1]hepta-2,5-diene{N-2,6-diisopropylphenyl(pentafluorophenyl)amidato}tricyclohexylphosphine rhodium(I)
• Formula: C45.5 H61.5 F5 N O P Rh
• Calculated formula: C45.5 H61.5 F5 N O P Rh
• Title of publication: Isocyanate deinsertion from κ(1)-O amidates: facile access to perfluoroaryl rhodium(i) complexes.
• Authors of publication: Drover, Marcus W.; Schafer, Laurel L.; Love, Jennifer A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 45
• Pages of publication: 19487 - 19493
• a: 9.9058 ± 0.0008 Å
• b: 21.0289 ± 0.0017 Å
• c: 21.6355 ± 0.0016 Å
• α: 102.878 ± 0.003°
• β: 99.532 ± 0.003°
• γ: 90.372 ± 0.003°
• Cell volume: 4328.4 ± 0.6 ų
• Cell temperature: 90 K
• Ambient diffraction temperature: 90 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0798
• Residual factor for significantly intense reflections: 0.0528
• Weighted residual factors for significantly intense reflections: 0.1349
• Weighted residual factors for all reflections included in the refinement: 0.1457
• Goodness-of-fit parameter for all reflections included in the refinement: 1.057
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No