Information card for entry 7036346

Structure parameters

• Common name: [Ni(η^3^-C~9~H~7~)(Cl)(AsPh~3~)]
• Chemical name: (tri-hapto-indenyl)-chloro-triphenylarsine-nickel (II)
• Formula: C27 H22 As Cl Ni
• Calculated formula: C27 H22 As Cl Ni
• SMILES: [Ni]1234([As](c5ccccc5)(c5ccccc5)c5ccccc5)(Cl)[cH]5[cH]1[cH]2[c]13cccc[c]451
• Title of publication: First examples of neutral and cationic indenyl nickel(ii) complexes bearing arsine or stibine ligands: highly active catalysts for the oligomerisation of styrene.
• Authors of publication: Gomes, Clara S. B.; Krishnamoorthy, Paramasivam; Silva, Leonel C.; Costa, Sandra I.; Gomes, Pedro T.; Jiménez-Tenorio, Manuel; Valerga, Pedro; Puerta, M. Carmen
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 39
• Pages of publication: 17015 - 17019
• a: 10.0199 ± 0.0012 Å
• b: 14.4995 ± 0.0017 Å
• c: 16.754 ± 0.002 Å
• α: 66.647 ± 0.002°
• β: 83.975 ± 0.002°
• γ: 89.327 ± 0.003°
• Cell volume: 2221.1 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0631
• Residual factor for significantly intense reflections: 0.0577
• Weighted residual factors for significantly intense reflections: 0.1272
• Weighted residual factors for all reflections included in the refinement: 0.1308
• Goodness-of-fit parameter for all reflections included in the refinement: 1.074
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No