Information card for entry 7037295

Structure parameters

• Formula: C34 H48 Cl3 N2 O0.5 Ru Si
• Calculated formula: C34 H48 Cl3 N2 O0.5 Ru Si
• Title of publication: NHC carbene supported half-sandwich hydridosilyl complexes of ruthenium: the impact of supporting ligands on SiH interligand interactions.
• Authors of publication: Mai, Van Hung; Kuzmina, Lyudmila G.; Churakov, Andrei V.; Korobkov, Ilia; Howard, Judith A. K.; Nikonov, Georgii I.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 45
• Journal issue: 1
• Pages of publication: 208 - 215
• a: 11.0661 ± 0.0006 Å
• b: 18.858 ± 0.001 Å
• c: 18.9389 ± 0.001 Å
• α: 110.994 ± 0.002°
• β: 102.836 ± 0.002°
• γ: 97.069 ± 0.002°
• Cell volume: 3507.4 ± 0.3 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0768
• Residual factor for significantly intense reflections: 0.0491
• Weighted residual factors for significantly intense reflections: 0.1171
• Weighted residual factors for all reflections included in the refinement: 0.1294
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No