Information card for entry 7037325

Structure parameters

• Formula: C18 H19 Cl Ge
• Calculated formula: C18 H19 Cl Ge
• SMILES: [Ge](Cl)(c1ccccc1)(c1ccccc1)C#CC(C)(C)C
• Title of publication: Functionalized alkynyl-chlorogermanes: hydrometallation, Ge-Cl bond activation, Ge-H bond formation and chlorine-tert-butyl exchange via a transient germyl cation.
• Authors of publication: Honacker, Christian; Qu, Zheng-Wang; Tannert, Jens; Layh, Marcus; Hepp, Alexander; Grimme, Stefan; Uhl, Werner
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 14
• Pages of publication: 6159 - 6174
• a: 9.1791 ± 0.0004 Å
• b: 9.8948 ± 0.0004 Å
• c: 10.2882 ± 0.0004 Å
• α: 79.7842 ± 0.0011°
• β: 66.5677 ± 0.001°
• γ: 87.3763 ± 0.0011°
• Cell volume: 843.46 ± 0.06 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.032
• Residual factor for significantly intense reflections: 0.0266
• Weighted residual factors for significantly intense reflections: 0.0631
• Weighted residual factors for all reflections included in the refinement: 0.0654
• Goodness-of-fit parameter for all reflections included in the refinement: 1.081
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No