Information card for entry 7037332

Structure parameters

• Formula: C26 H42 Cl Ga Ge
• Calculated formula: C26 H42 Cl Ga Ge
• SMILES: [Ge]1([Cl][Ga](/C1=C/C(C)(C)C)(C(C)(C)C)C(C)(C)C)(C#CC(C)(C)C)c1ccccc1
• Title of publication: Functionalized alkynyl-chlorogermanes: hydrometallation, Ge-Cl bond activation, Ge-H bond formation and chlorine-tert-butyl exchange via a transient germyl cation.
• Authors of publication: Honacker, Christian; Qu, Zheng-Wang; Tannert, Jens; Layh, Marcus; Hepp, Alexander; Grimme, Stefan; Uhl, Werner
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 14
• Pages of publication: 6159 - 6174
• a: 10.1387 ± 0.0004 Å
• b: 10.6816 ± 0.0004 Å
• c: 14.032 ± 0.0005 Å
• α: 81.233 ± 0.001°
• β: 75.177 ± 0.001°
• γ: 89.661 ± 0.001°
• Cell volume: 1451.02 ± 0.09 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0347
• Residual factor for significantly intense reflections: 0.0265
• Weighted residual factors for significantly intense reflections: 0.0672
• Weighted residual factors for all reflections included in the refinement: 0.0707
• Goodness-of-fit parameter for all reflections included in the refinement: 1.041
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No