Information card for entry 7037649

Structure parameters

• Formula: C24 H18 Cl2 O6 P2 W
• Calculated formula: C24 H18 Cl2 O6 P2 W
• SMILES: [W]([PH](P(=O)(c1ccccc1)c1ccccc1)c1ccccc1)(C#[O])(C#[O])(C#[O])(C#[O])C#[O].ClCCl
• Title of publication: Insertion of phosphinidene complexes into the P-H bond of secondary phosphine oxides: a new version of the phospha-Wittig synthesis of P[double bond, length as m-dash]C double bonds.
• Authors of publication: Hao, Yanwei; Wu, Di; Tian, Rongqiang; Duan, Zheng; Mathey, François
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 3
• Pages of publication: 891 - 893
• a: 6.34581 ± 0.00018 Å
• b: 19.8 ± 0.0006 Å
• c: 21.5196 ± 0.0006 Å
• α: 90°
• β: 97.974 ± 0.003°
• γ: 90°
• Cell volume: 2677.73 ± 0.14 ų
• Cell temperature: 291 ± 2 K
• Ambient diffraction temperature: 291.15 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0501
• Residual factor for significantly intense reflections: 0.0364
• Weighted residual factors for significantly intense reflections: 0.0678
• Weighted residual factors for all reflections included in the refinement: 0.072
• Goodness-of-fit parameter for all reflections included in the refinement: 1.096
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No