Information card for entry 7037811

Structure parameters

• Formula: C80 H69 Cl12 O8 P3 Pt5 Sn6
• Calculated formula: C80 H69 Cl12 O8 P3 Pt5 Sn6
• SMILES: [Pt]12345([Pt]6789%10%11([Pt]%12%13%14%15%161([Pt]1%17%18%1926([Pt]7%12([Sn]9%14(Cl)(Cl)[O]([Sn]38%13(Cl)Cl)C)([Sn]%11%17(Cl)(Cl)[O]([Sn]4%101(Cl)Cl)C)([Sn]%16%19(Cl)(Cl)[O]([Sn]5%15%18(Cl)Cl)C)C#[O])C#[O])C#[O])C#[O])C#[O].[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Platinum carbonyl clusters stabilized by Sn(ii)-based fragments: syntheses and structures of [Pt6(CO)6(SnCl2)2(SnCl3)4](4-), [Pt9(CO)8(SnCl2)3(SnCl3)2(Cl2SnOCOSnCl2)](4-) and [Pt10(CO)14{Cl2Sn(OH)SnCl2}2](2.).
• Authors of publication: Bortoluzzi, Marco; Ceriotti, Alessandro; Ciabatti, Iacopo; Della Pergola, Roberto; Femoni, Cristina; Carmela Iapalucci, Maria; Storione, Alba; Zacchini, Stefano
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 12
• Pages of publication: 5001 - 5013
• a: 14.0022 ± 0.0002 Å
• b: 14.5742 ± 0.0003 Å
• c: 47.1561 ± 0.0008 Å
• α: 90°
• β: 92.275 ± 0.001°
• γ: 90°
• Cell volume: 9615.6 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0591
• Residual factor for significantly intense reflections: 0.0376
• Weighted residual factors for significantly intense reflections: 0.0667
• Weighted residual factors for all reflections included in the refinement: 0.0738
• Goodness-of-fit parameter for all reflections included in the refinement: 1.063
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No