Information card for entry 7038115

Structure parameters

• Formula: C66 H64 F84 O20 Sm6
• Calculated formula: C66 H64 F84 O20 Sm6
• SMILES: [Sm]12345([O](C(C(F)(F)F)C(F)(F)F)[Sm]67([O](C(C(F)(F)F)C(F)(F)F)[Sm]([O]16C(C(F)(F)F)C([F]3)(F)F)([O]47C(C(F)(F)F)C([F]5)(F)F)([O]2C(C(F)(F)F)C(F)(F)F)([O]1CCCC1)[O](CC)CC)(OC(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)C(F)(F)F)[O]1CCCC1.[Sm]123([O](C(C(F)(F)F)C(F)(F)F)[Sm]4567([O](C(C(F)(F)F)C(F)(F)F)[Sm]([O]26C(C(F)(F)F)C([F]7)(F)F)([O]34C(C(F)(F)F)C(F)([F]5)F)([O]1C(C(F)(F)F)C(F)(F)F)([O]1CCCC1)[O]1CCCC1)[O]1CCCC1)(OC(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)C(F)(F)F
• Title of publication: Synthesis, structure and luminescent properties of lanthanide fluoroalkoxides.
• Authors of publication: Kuzyaev, D. M.; Balashova, T. V.; Burin, M. E.; Fukin, G. K.; Rumyantcev, R. V.; Pushkarev, A. P.; Ilichev, V. A.; Grishin, I. D.; Vorozhtsov, D. L.; Bochkarev, M. N.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 8
• Pages of publication: 3464 - 3472
• a: 10.7448 ± 0.0004 Å
• b: 13.4413 ± 0.0005 Å
• c: 19.2506 ± 0.0008 Å
• α: 90.229 ± 0.001°
• β: 102.887 ± 0.001°
• γ: 94.797 ± 0.001°
• Cell volume: 2699.99 ± 0.18 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 1
• Hermann-Mauguin space group symbol: P 1
• Hall space group symbol: P 1
• Residual factor for all reflections: 0.082
• Residual factor for significantly intense reflections: 0.0603
• Weighted residual factors for significantly intense reflections: 0.1527
• Weighted residual factors for all reflections included in the refinement: 0.1647
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No