Information card for entry 7038186

Structure parameters

• Formula: C32 H39 Cl4 I3 N7 Rh
• Calculated formula: C30 H35 I3 N7 Rh
• Title of publication: Transfer hydrogenation with abnormal dicarbene rhodium(iii) complexes containing ancillary and modular poly-pyridine ligands.
• Authors of publication: Farrell, Kevin; Melle, Philipp; Gossage, Robert A.; Müller-Bunz, Helge; Albrecht, Martin
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 11
• Pages of publication: 4570 - 4579
• a: 11.0304 ± 0.0003 Å
• b: 13.3992 ± 0.0004 Å
• c: 14.0098 ± 0.0004 Å
• α: 85.577 ± 0.003°
• β: 78 ± 0.003°
• γ: 80.837 ± 0.003°
• Cell volume: 1997.46 ± 0.1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0491
• Residual factor for significantly intense reflections: 0.0473
• Weighted residual factors for significantly intense reflections: 0.1282
• Weighted residual factors for all reflections included in the refinement: 0.1296
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No