Information card for entry 7038523

Structure parameters

• Chemical name: [Pt2Ag2(bpy)2(Me2pz)4](PF6)2
• Formula: C43 H50 Ag2 F12 N12 O P2 Pt2
• Calculated formula: C43 H50 Ag2 F12 N12 O P2 Pt2
• SMILES: [Ag]([n]1n([Pt]2([n]3c(c4[n]2cccc4)cccc3)n2[n](c(cc2C)C)[Ag]2)c(cc1C)C)[n]1n([Pt]3([n]4c(c5[n]3cccc5)cccc4)n3[n]2c(cc3C)C)c(cc1C)C.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].O=C(C)C
• Title of publication: Different structural preference of Ag(i) and Au(i) in neutral and cationic luminescent heteropolynuclear platinum(ii) complexes: Z (U)-shaped Pt2M2 type vs. trinuclear PtM2 type.
• Authors of publication: Nishihara, Kazuki; Ueda, Misa; Higashitani, Ami; Nakao, Yoshihide; Arikawa, Yasuhiro; Horiuchi, Shinnosuke; Sakuda, Eri; Umakoshi, Keisuke
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 12
• Pages of publication: 4978 - 4982
• a: 13.979 ± 0.002 Å
• b: 17.286 ± 0.003 Å
• c: 21.804 ± 0.003 Å
• α: 90°
• β: 94.44 ± 0.003°
• γ: 90°
• Cell volume: 5252.9 ± 1.4 ų
• Cell temperature: 93 K
• Ambient diffraction temperature: 93 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0512
• Residual factor for significantly intense reflections: 0.0416
• Weighted residual factors for significantly intense reflections: 0.0748
• Weighted residual factors for all reflections included in the refinement: 0.0793
• Goodness-of-fit parameter for all reflections included in the refinement: 1.104
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No