Gyroscope like molecules consisting of trigonal or square planar osmium rotators within three-spoked dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties.
Authors of publication
Fiedler, Tobias; Bhuvanesh, Nattamai; Hampel, Frank; Reibenspies, Joseph H.; Gladysz, John A.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2016
Journal volume
45
Journal issue
16
Pages of publication
7131 - 7147
a
13.496 ± 0.008 Å
b
17.609 ± 0.01 Å
c
19.88 ± 0.011 Å
α
90°
β
96.549 ± 0.007°
γ
90°
Cell volume
4694 ± 5 Å3
Cell temperature
110 ± 2 K
Ambient diffraction temperature
110 ± 2 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0341
Residual factor for significantly intense reflections
0.0197
Weighted residual factors for significantly intense reflections
0.0437
Weighted residual factors for all reflections included in the refinement
0.0522
Goodness-of-fit parameter for all reflections included in the refinement
