Information card for entry 7038973

Structure parameters

• Formula: C90 H94 Cl4 F12 N2 P10 Pt3
• Calculated formula: C90 H94 Cl4 F12 N2 P10 Pt3
• SMILES: C(#[N]C(C)(C)C)[Pt]123[P](c4ccccc4)(c4ccccc4)C[P]4([Pt]51[P]1(C[P](c6ccccc6)(c6ccccc6)[Pt]5(C#[N]C(C)(C)C)([P](C1)(c1ccccc1)c1ccccc1)[P](C4)(c1ccccc1)c1ccccc1)C[P]3(c1ccccc1)c1ccccc1)C[P]2(c1ccccc1)c1ccccc1.[P](F)(F)(F)(F)(F)[F-].C(Cl)Cl.[P](F)(F)(F)(F)(F)[F-].C(Cl)Cl
• Title of publication: Electron-rich linear triplatinum complexes stabilized by a spinning tetraphosphine, tris(diphenylphosphinomethyl)phosphine.
• Authors of publication: Tanase, Tomoaki; Koike, Kanako; Uegaki, Miho; Hatada, Satoko; Nakamae, Kanako; Kure, Bunsho; Ura, Yasuyuki; Nakajima, Takayuki
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 17
• Pages of publication: 7209 - 7214
• a: 11.5968 ± 0.0009 Å
• b: 21.9132 ± 0.0013 Å
• c: 18.8936 ± 0.0015 Å
• α: 90°
• β: 97.8 ± 0.004°
• γ: 90°
• Cell volume: 4756.9 ± 0.6 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0367
• Weighted residual factors for all reflections included in the refinement: 0.1089
• Goodness-of-fit parameter for all reflections included in the refinement: 0.994
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No