A novel 1,3,5-triaminocyclohexane-based tripodal ligand forms a unique tetra(pyrazolate)-bridged tricopper(ii) core: solution equilibrium, structure and catecholase activity.
Authors of publication
Szorcsik, Attila; Matyuska, Ferenc; Bényei, Attila; Nagy, Nóra V; Szilágyi, Róbert K; Gajda, Tamás
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2016
Journal volume
45
Journal issue
38
Pages of publication
14998 - 15012
a
13.174 ± 0.005 Å
b
28.762 ± 0.005 Å
c
13.484 ± 0.005 Å
α
90 ± 0.005°
β
105.06 ± 0.005°
γ
90 ± 0.005°
Cell volume
4934 ± 3 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.07
Residual factor for significantly intense reflections
0.0691
Weighted residual factors for all reflections included in the refinement
0.2087
Goodness-of-fit parameter for all reflections included in the refinement
