Information card for entry 7041011

Structure parameters

• Formula: C22 H34 Cl2 N4 P2 Pt
• Calculated formula: C22 H34 Cl2 N4 P2 Pt
• SMILES: [Pt](Cl)(Cl)([P]1(N(CCN1C)C)c1ccc(cc1)C)[P]1(N(CCN1C)C)c1ccc(cc1)C
• Title of publication: R/X exchange reactions in cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt), via a phosphenium intermediate.
• Authors of publication: Itazaki, Masumi; Tsuchida, Noriko; Shigesato, Yuka; Takano, Keiko; Nakazawa, Hiroshi
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 48
• Pages of publication: 19216 - 19220
• a: 10.0497 ± 0.0004 Å
• b: 32.6793 ± 0.0015 Å
• c: 16.1968 ± 0.0007 Å
• α: 90°
• β: 91.935 ± 0.002°
• γ: 90°
• Cell volume: 5316.3 ± 0.4 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0629
• Residual factor for significantly intense reflections: 0.0484
• Weighted residual factors for significantly intense reflections: 0.0668
• Weighted residual factors for all reflections included in the refinement: 0.0701
• Goodness-of-fit parameter for all reflections included in the refinement: 1.191
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No