Information card for entry 7042521

Structure parameters

• Chemical name: cis-hydrogen-bridged bis(silylene)ruthenium complex
• Formula: C21 H40 O Ru Si2
• Calculated formula: C21 H40 O Ru Si2
• SMILES: [Ru]12345([Si]6([Si]1(C)(C(C)(C)C)[H]6)(C)C(C)(C)C)(C#[O])[c]1([c]2([c]3([c]4([c]51C)C)C)C)C
• Title of publication: Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M‒Si‒H‒Si four-membered ring
• Authors of publication: Hashimoto, Hisako; Komura, Katsuto; Ishizaki, Takatoshi; Odagiri, Yuto; Tobita, Hiromi
• Journal of publication: Dalton Trans.
• Year of publication: 2017
• a: 8.3493 ± 0.0002 Å
• b: 9.6791 ± 0.0001 Å
• c: 16.9592 ± 0.0002 Å
• α: 98.5709 ± 0.001°
• β: 92.142 ± 0.0009°
• γ: 114.172 ± 0.0015°
• Cell volume: 1229.02 ± 0.04 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0539
• Residual factor for significantly intense reflections: 0.0429
• Weighted residual factors for significantly intense reflections: 0.0872
• Weighted residual factors for all reflections included in the refinement: 0.0908
• Goodness-of-fit parameter for all reflections included in the refinement: 1.142
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No