Information card for entry 7042657

Structure parameters

• Formula: C54 H68 Cl O3 P2 Rh Si2
• Calculated formula: C54 H68 Cl O3 P2 Rh Si2
• Title of publication: A family of rhodium and iridium complexes with semirigid benzylsilyl phosphines: from bidentate to tetradentate coordination modes
• Authors of publication: Corona-González, María Vicky; Zamora-Moreno, Julio; Cuevas-Chávez, Cynthia A.; Rufino-Felipe, Ernesto; Mothes-Martin, Emmanuelle; Coppel, Yannick; Muñoz-Hernández, Miguel A.; Vendier, Laure; Flores-Alamo, Marcos; Grellier, Mary; Sabo-Etienne, Sylviane; Montiel-Palma, Virginia
• Journal of publication: Dalton Trans.
• Year of publication: 2017
• a: 20.649 ± 0.0006 Å
• b: 17.2473 ± 0.0004 Å
• c: 13.9539 ± 0.0004 Å
• α: 90°
• β: 91.939 ± 0.003°
• γ: 90°
• Cell volume: 4966.7 ± 0.2 ų
• Cell temperature: 100.46 ± 0.1 K
• Ambient diffraction temperature: 100.46 ± 0.1 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0399
• Residual factor for significantly intense reflections: 0.0341
• Weighted residual factors for significantly intense reflections: 0.0833
• Weighted residual factors for all reflections included in the refinement: 0.0868
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No