Information card for entry 7042954

Structure parameters

• Formula: C25 H38 N2 S Si
• Calculated formula: C25 H38 N2 S Si
• SMILES: S=[Si]1([N](=C(N1C(C)(C)C)c1ccccc1)C(C)(C)C)C1(C(=C(C(=C1C)C)C)C)C
• Title of publication: Reactivity studies of silylene [PhC(NtBu)2](C5Me5)Si - reactions with [M(COD)Cl]2 (M = Rh(i), Ir(i)), S, Se, Te, and BH3.
• Authors of publication: Kaufmann, Sebastian; Schäfer, Sebastian; Gamer, Michael T.; Roesky, Peter W.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2017
• a: 9.0839 ± 0.001 Å
• b: 11.1221 ± 0.0011 Å
• c: 13.3222 ± 0.0015 Å
• α: 90.853 ± 0.009°
• β: 97.883 ± 0.009°
• γ: 111.01 ± 0.008°
• Cell volume: 1241.6 ± 0.2 ų
• Cell temperature: 210 K
• Ambient diffraction temperature: 210 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0642
• Residual factor for significantly intense reflections: 0.0407
• Weighted residual factors for significantly intense reflections: 0.107
• Weighted residual factors for all reflections included in the refinement: 0.1114
• Goodness-of-fit parameter for all reflections included in the refinement: 0.933
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No