Information card for entry 7045316

Structure parameters

• Formula: C106 H138 Cl4 Co2 N8 O P6 Si4
• Calculated formula: C106 H138 Cl4 Co2 N8 O P6 Si4
• Title of publication: Synthesis and catalytic activity of N-heterocyclic silylene (NHSi) cobalt hydride for Kumada coupling reactions.
• Authors of publication: Qi, Xinghao; Sun, Hongjian; Li, Xiaoyan; Fuhr, Olaf; Fenske, Dieter
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 8
• Pages of publication: 2581 - 2588
• a: 13.9433 ± 0.0005 Å
• b: 17.2555 ± 0.0007 Å
• c: 24.5173 ± 0.001 Å
• α: 99.18 ± 0.003°
• β: 99.723 ± 0.003°
• γ: 103.83 ± 0.003°
• Cell volume: 5521 ± 0.4 ų
• Cell temperature: 150.15 K
• Ambient diffraction temperature: 150.15 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1749
• Residual factor for significantly intense reflections: 0.0949
• Weighted residual factors for significantly intense reflections: 0.2452
• Weighted residual factors for all reflections included in the refinement: 0.3026
• Goodness-of-fit parameter for all reflections included in the refinement: 0.847
• Diffraction radiation wavelength: 1.54186 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No