Information card for entry 7046680

Structure parameters

• Common name: iPr2PPrDINi
• Formula: C22 H46 N2 Ni P2
• Calculated formula: C22 H46 N2 Ni P2
• Title of publication: Carbonyl and ester C-O bond hydrosilylation using κ⁴-diimine nickel catalysts.
• Authors of publication: Rock, Christopher L.; Groy, Thomas L.; Trovitch, Ryan J.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 26
• Pages of publication: 8807 - 8816
• a: 9.0477 ± 0.0005 Å
• b: 10.1518 ± 0.0006 Å
• c: 15.4698 ± 0.0009 Å
• α: 94.42 ± 0.001°
• β: 100.197 ± 0.001°
• γ: 115.723 ± 0.001°
• Cell volume: 1240.76 ± 0.12 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0462
• Residual factor for significantly intense reflections: 0.0416
• Weighted residual factors for significantly intense reflections: 0.1037
• Weighted residual factors for all reflections included in the refinement: 0.1071
• Goodness-of-fit parameter for all reflections included in the refinement: 1.07
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No