Information card for entry 7048007

Structure parameters

• Formula: C35 H47 Br F6 N Ni O2 P2 S Sb
• Calculated formula: C35 H47 Br F6 N Ni O2 P2 S Sb
• Title of publication: Redox-state dependent activation of silanes and ammonia with reverse polarity (PC_carbeneP)Ni complexes: electrophilic vs. nucleophilic carbenes.
• Authors of publication: LaPierre, Etienne A.; Piers, Warren E.; Gendy, Chris
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 46
• Pages of publication: 16789 - 16797
• a: 11.7793 ± 0.0005 Å
• b: 15.5651 ± 0.0009 Å
• c: 20.8787 ± 0.0011 Å
• α: 90°
• β: 90.523 ± 0.003°
• γ: 90°
• Cell volume: 3827.9 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 10
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0481
• Residual factor for significantly intense reflections: 0.0314
• Weighted residual factors for significantly intense reflections: 0.0654
• Weighted residual factors for all reflections included in the refinement: 0.0723
• Goodness-of-fit parameter for all reflections included in the refinement: 1.01
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No