Information card for entry 7048010

Structure parameters

• Formula: C28 H40 Br Ni P2
• Calculated formula: C28 H40 Br Ni P2
• Title of publication: Redox-state dependent activation of silanes and ammonia with reverse polarity (PC_carbeneP)Ni complexes: electrophilic vs. nucleophilic carbenes.
• Authors of publication: LaPierre, Etienne A.; Piers, Warren E.; Gendy, Chris
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 46
• Pages of publication: 16789 - 16797
• a: 11.019 ± 0.0006 Å
• b: 11.1636 ± 0.0007 Å
• c: 13.0424 ± 0.0008 Å
• α: 107.237 ± 0.002°
• β: 98.206 ± 0.002°
• γ: 111.768 ± 0.002°
• Cell volume: 1364.11 ± 0.15 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0478
• Residual factor for significantly intense reflections: 0.0334
• Weighted residual factors for significantly intense reflections: 0.0748
• Weighted residual factors for all reflections included in the refinement: 0.0801
• Goodness-of-fit parameter for all reflections included in the refinement: 1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No