Information card for entry 7048908

Structure parameters

• Formula: C72 H79 B Cl2 F24 N P2 Rh
• Calculated formula: C72 H79 B Cl2 F24 N P2 Rh
• Title of publication: A convenient method for the generation of {Rh(PNP)}⁺ and {Rh(PONOP)}⁺ fragments: reversible formation of vinylidene derivatives.
• Authors of publication: Gyton, Matthew R.; Hood, Thomas M.; Chaplin, Adrian B.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 9
• Pages of publication: 2877 - 2880
• a: 12.48767 ± 0.00018 Å
• b: 17.2204 ± 0.0003 Å
• c: 20.1861 ± 0.0003 Å
• α: 107.145 ± 0.0014°
• β: 107.196 ± 0.0014°
• γ: 99.1527 ± 0.0012°
• Cell volume: 3815.67 ± 0.12 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0451
• Residual factor for significantly intense reflections: 0.038
• Weighted residual factors for significantly intense reflections: 0.0932
• Weighted residual factors for all reflections included in the refinement: 0.0981
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No