Information card for entry 7049121

Structure parameters

• Formula: C78 H110 F24 N14 O3 P6 Rh2
• Calculated formula: C78 H110 F24 N14 O3 P6 Rh2
• Title of publication: Unbridged Rh(ii)-Rh(ii) complexes of N-heterocyclic carbenes and reactions with O₂ to form dirhodium(μ-η¹:η¹-O₂) complexes.
• Authors of publication: Yi, Xiaofei; Liu, Bin; Chen, Kai; Chen, Wei; Chen, Wanzhi
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 12
• Pages of publication: 3835 - 3839
• a: 13.1037 ± 0.0015 Å
• b: 14.8822 ± 0.0017 Å
• c: 15.3583 ± 0.0011 Å
• α: 104.336 ± 0.008°
• β: 111.184 ± 0.009°
• γ: 106.435 ± 0.01°
• Cell volume: 2465.1 ± 0.6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0659
• Residual factor for significantly intense reflections: 0.0512
• Weighted residual factors for significantly intense reflections: 0.1314
• Weighted residual factors for all reflections included in the refinement: 0.1456
• Goodness-of-fit parameter for all reflections included in the refinement: 1.056
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No