Information card for entry 7049500

Structure parameters

• Chemical name: Th(TIG)2(OCH2SiMe3)2
• Formula: C34 H78 N6 O2 Si2 Th
• Calculated formula: C34 H78 N6 O2 Si2 Th
• Title of publication: Dioxygen reacts with metal-carbon bonds in thorium dialkyls to produce bis(alkoxides).
• Authors of publication: Settineri, Nicholas S.; Shiau, Angela A.; Arnold, John
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 17
• Pages of publication: 5569 - 5573
• a: 23.921 ± 0.005 Å
• b: 11.822 ± 0.002 Å
• c: 19.372 ± 0.004 Å
• α: 90°
• β: 126.69 ± 0.006°
• γ: 90°
• Cell volume: 4392.9 ± 1.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0201
• Residual factor for significantly intense reflections: 0.0194
• Weighted residual factors for significantly intense reflections: 0.0463
• Weighted residual factors for all reflections included in the refinement: 0.0466
• Goodness-of-fit parameter for all reflections included in the refinement: 1.118
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No