Information card for entry 7049549

Structure parameters

• Formula: C32 H48 Co2 Cu3 Mo10 N8 O50
• Calculated formula: C32 H48 Co2 Cu3 Mo10 N8 O50
• Title of publication: Syntheses, structures and catalytic properties of Evans-Showell-type polyoxometalate-based 3D metal-organic complexes constructed from the semi-rigid bis(pyridylformyl)piperazine ligand and transition metals.
• Authors of publication: Li, Feng-Cai; Tan, Li-Kun; Li, Xi-Li; Kong, Hua-Jie; Ge, Li-Ming; Yue, Ling-Yu; Han, Li-Feng
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 17
• Pages of publication: 5831 - 5841
• a: 12.1598 ± 0.0005 Å
• b: 14.1021 ± 0.0006 Å
• c: 23.8608 ± 0.0012 Å
• α: 78.079 ± 0.004°
• β: 82.282 ± 0.004°
• γ: 83.825 ± 0.003°
• Cell volume: 3953.6 ± 0.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 298.15 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1279
• Residual factor for significantly intense reflections: 0.0923
• Weighted residual factors for significantly intense reflections: 0.2229
• Weighted residual factors for all reflections included in the refinement: 0.2481
• Goodness-of-fit parameter for all reflections included in the refinement: 1.06
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No