Information card for entry 7050308

Structure parameters

• Common name: [Br(PPh3)(Py)Pd]2
• Chemical name: Bromo(triphenylposphine)(2-pyridine)Paladium dimer
• Formula: C51.5 H41.5 Br2 F N2.5 P2 Pd2
• Calculated formula: C51.5 H41.5 Br2 F N2.5 P2 Pd2
• Title of publication: A new precatalyst for the Suzuki reaction—a pyridyl-bridged dinuclear palladium complex as a source of mono-ligated palladium(0)
• Authors of publication: Andrew Beeby; Sylvia Bettington; Ian J. S. Fairlamb; Andrés E. Goeta; Anant R. Kapdi; Elina H. Niemelä; Amber L. Thompson
• Journal of publication: New J. Chem.
• Year of publication: 2004
• Journal volume: 28
• Journal issue: 5
• Pages of publication: 600 - 605
• a: 10.4525 ± 0.0004 Å
• b: 13.0911 ± 0.0005 Å
• c: 17.7535 ± 0.0006 Å
• α: 81.517 ± 0.001°
• β: 78.849 ± 0.002°
• γ: 70.818 ± 0.001°
• Cell volume: 2241.84 ± 0.14 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.068
• Residual factor for significantly intense reflections: 0.0431
• Weighted residual factors for significantly intense reflections: 0.0898
• Weighted residual factors for all reflections included in the refinement: 0.1002
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No