Information card for entry 7050513

Structure parameters

• Common name: Di(tetra(dimethylamido)phosphonium)(2+) 1,8- Bis(trichlorostannato)-2,7,9,14,15,20-hexaoxa-3,6,10,13,16,19-hexaaza- 4,5,11,12,17,18-hexachlorobicyclo-(6.6.6)eicosa-3,5,10,12,16,18-hexaene iron(ii) (2-)
• Formula: C22 H48 Cl12 Fe N14 O6 P2 Sn2
• Calculated formula: C22 H48 Cl12 Fe N14 O6 P2 Sn2
• Title of publication: First trigonal-antiprismatic tris-dichloroglyoximate iron(ii) clathrochelate and its reactivity in nucleophilic substitution reactionsElectronic supplementary information (ESI) available: EXAFS oscillations, k2?(k), and RDA curves of six boron- and tin-capped iron(ii) clathrochelates. See http://www.rsc.org/suppdata/nj/b2/b211623e/
• Authors of publication: Voloshin, Yan Z.; Varzatskii, Oleg A.; Palchik, Aleksei V.; Strizhakova, Nataly G.; Vorontsov, Ivan I.; Antipin, Mikhail Yu.; Kochubey, Dmitry I.; Novgorodov, Boris N.
• Journal of publication: New Journal of Chemistry
• Year of publication: 2003
• Journal volume: 27
• Journal issue: 7
• Pages of publication: 1148
• a: 19.498 ± 0.009 Å
• b: 8.584 ± 0.004 Å
• c: 29.979 ± 0.013 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5018 ± 4 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 8
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.0806
• Residual factor for significantly intense reflections: 0.0541
• Weighted residual factors for significantly intense reflections: 0.1165
• Weighted residual factors for all reflections included in the refinement: 0.1269
• Goodness-of-fit parameter for all reflections included in the refinement: 0.927
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No