Information card for entry 7051075

Structure parameters

• Formula: C45 H51 O3 P2 Rh
• Calculated formula: C45 H51 O3 P2 Rh
• SMILES: [Rh]1234([P](Oc5ccccc5)(Oc5ccccc5)Oc5ccccc5)([P](C(C)C)(C(C)C)C(C)C)[cH]5[cH]1[cH]2[cH]3[c]45C(c1ccccc1)c1ccccc1
• Title of publication: PX3-induced migratory insertion reactions of half-sandwich-type carbenerhodium(I) complexes
• Authors of publication: Herber, Ulrich; Guerrero Sanchez, Rita; Gevert, Olaf; Laubender, Matthias; Werner, Helmut
• Journal of publication: New Journal of Chemistry
• Year of publication: 2001
• Journal volume: 25
• Journal issue: 3
• Pages of publication: 396
• a: 10.17 ± 0.003 Å
• b: 11.177 ± 0.002 Å
• c: 17.401 ± 0.003 Å
• α: 85.68 ± 0.01°
• β: 84.78 ± 0.02°
• γ: 88.03 ± 0.02°
• Cell volume: 1963.4 ± 0.8 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1115
• Residual factor for significantly intense reflections: 0.073
• Weighted residual factors for all reflections: 0.1943
• Weighted residual factors for significantly intense reflections: 0.1633
• Goodness-of-fit parameter for all reflections: 1.068
• Goodness-of-fit parameter for significantly intense reflections: 1.084
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No