Information card for entry 7052415

Structure parameters

• Formula: C25 H52 N2 Os P2
• Calculated formula: C25 H50 N2 Os P2
• SMILES: [Os]1(Nc2ccccc2N1C)([P](C(C)C)(C(C)C)C(C)C)[P](C(C)C)(C(C)C)C(C)C
• Title of publication: New d4 dihydrides of Ru(iv) and Os(iv) with ?-donor ligands: M(H)2(chelate)(PiPr3)2 with chelate =ortho-XYC6H4 with X, Y = O, NR; R = H or CH3
• Authors of publication: Ferrando-Miguel, German; Wu, Peng; Huffman, John C.; Caulton, Kenneth G.
• Journal of publication: New Journal of Chemistry
• Year of publication: 2005
• Journal volume: 29
• Journal issue: 1
• Pages of publication: 193
• a: 8.9882 ± 0.0003 Å
• b: 21.8475 ± 0.0009 Å
• c: 14.1438 ± 0.0006 Å
• α: 90°
• β: 97.422 ± 0.001°
• γ: 90°
• Cell volume: 2754.14 ± 0.19 ų
• Cell temperature: 113 ± 2 K
• Ambient diffraction temperature: 113 ± 2 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0389
• Residual factor for significantly intense reflections: 0.0322
• Weighted residual factors for significantly intense reflections: 0.0674
• Weighted residual factors for all reflections included in the refinement: 0.0698
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No