Information card for entry 7054344

Structure parameters

• Common name: Tetrakis(dibenzonitriletheobrominesilver(I))decatungstate benzonitrile
• Chemical name: Tetrakis(dibenzonitriletheobrominesilver(I))di-mu5-oxo-icosa- mu-oxo-decaoxodecatungstate benzonitrile
• Formula: C91 H77 Ag4 N25 O40 W10
• Calculated formula: C91 H76 Ag4 N25 O40 W10
• Title of publication: Organoamine silver(i) decatungstate structures: remarkable chemoselectivity and the exploration of the intramolecular redox reaction upon thermolysis
• Authors of publication: Kulikov, Vladislav; Meyer, Gerd
• Journal of publication: New Journal of Chemistry
• Year of publication: 2014
• Journal volume: 38
• Journal issue: 8
• Pages of publication: 3408
• a: 10.7971 ± 0.0005 Å
• b: 14.5 ± 0.0006 Å
• c: 20.1073 ± 0.0008 Å
• α: 97.929 ± 0.003°
• β: 93.069 ± 0.003°
• γ: 110.612 ± 0.003°
• Cell volume: 2900.5 ± 0.2 ų
• Cell temperature: 170 ± 2 K
• Ambient diffraction temperature: 170 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.095
• Residual factor for significantly intense reflections: 0.044
• Weighted residual factors for significantly intense reflections: 0.0845
• Weighted residual factors for all reflections included in the refinement: 0.099
• Goodness-of-fit parameter for all reflections included in the refinement: 0.846
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No