Amido rare-earth(iii) and Ca(ii) complexes coordinated by tridentate amidinate ligands: synthesis, structure, and catalytic activity in the ring-opening polymerization of rac-lactide and ε-caprolactone
Authors of publication
Rad’kova, Natalia Yu.; Kovylina, Tatyana A.; Shavyrin, Andrei S.; Cherkasov, Anton V.; Fukin, Georgy K.; Lyssenko, Konstantin A.; Trifonov, Alexander A.
Journal of publication
New Journal of Chemistry
Year of publication
2020
Journal volume
44
Journal issue
19
Pages of publication
7811 - 7822
a
20.9858 ± 0.0013 Å
b
11.6699 ± 0.0007 Å
c
20.5963 ± 0.0013 Å
α
90°
β
114.895 ± 0.001°
γ
90°
Cell volume
4575.4 ± 0.5 Å3
Cell temperature
120 ± 2 K
Ambient diffraction temperature
120 ± 2 K
Number of distinct elements
6
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.0271
Residual factor for significantly intense reflections
0.0236
Weighted residual factors for significantly intense reflections
0.0569
Weighted residual factors for all reflections included in the refinement
0.0579
Goodness-of-fit parameter for all reflections included in the refinement
