Synthesis, crystal structures, photophysical, electrochemical studies, DFT and TD-DFT calculations and Hirshfeld analysis of new 2,2′:6′,2′′-terpyridine ligands with pendant 4′-(trimethoxyphenyl) groups and their homoleptic ruthenium complexes
Authors of publication
Ramesh, Golla; P., Raghavendra Kumar; Pillegowda, Manohar; Periyasamy, Ganga; Suchetan, P. A.; Butcher, R. J.; Foro, Sabine; Nagaraju, G.
Journal of publication
New Journal of Chemistry
Year of publication
2020
Journal volume
44
Journal issue
27
Pages of publication
11471 - 11489
a
8.8332 ± 0.0005 Å
b
17.4183 ± 0.0009 Å
c
17.9294 ± 0.0009 Å
α
63.3 ± 0.004°
β
87.46 ± 0.005°
γ
89.376 ± 0.006°
Cell volume
2461.9 ± 0.2 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
7
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0511
Residual factor for significantly intense reflections
0.0389
Weighted residual factors for significantly intense reflections
0.1011
Weighted residual factors for all reflections included in the refinement
0.1072
Goodness-of-fit parameter for all reflections included in the refinement
