Information card for entry 7060254

Structure parameters

• Formula: C64 H108 Ni2 P4 Si4
• Calculated formula: C64 H108 Ni2 P4 Si4
• SMILES: [Ni]12([P](CC[P]1(C1CCCCC1)C1CCCCC1)(C1CCCCC1)C1CCCCC1)[Si@H]1[Si@@H]3[Ni]4([P](CC[P]4(C4CCCCC4)C4CCCCC4)(C4CCCCC4)C4CCCCC4)[Si@@H]([Si@H]2c2c3cccc2)c2c1cccc2.[Ni]12([P](CC[P]1(C1CCCCC1)C1CCCCC1)(C1CCCCC1)C1CCCCC1)[Si@@H]1[Si@H]3[Ni]4([P](CC[P]4(C4CCCCC4)C4CCCCC4)(C4CCCCC4)C4CCCCC4)[Si@H]([Si@@H]2c2c3cccc2)c2c1cccc2
• Title of publication: Trapping of two mononuclear silyl platinum(ii)/palladium(ii) complexes and a unique dinuclear bis(μ2-disilene)(silyl)nickel(ii) complex
• Authors of publication: Song, Hao; Zhang, Sen-Yu; Gu, Peng-Fei; Wu, Hua-Yu; Wang, Zi-Kun; Wang, Shi; Wang, Zheng; Gu, Yu-Yang; Li, Yong-Hua
• Journal of publication: New Journal of Chemistry
• Year of publication: 2020
• Journal volume: 44
• Journal issue: 46
• Pages of publication: 20351 - 20357
• a: 11.74 ± 0.002 Å
• b: 15.22 ± 0.003 Å
• c: 21.43 ± 0.004 Å
• α: 70.53 ± 0.03°
• β: 80.01 ± 0.03°
• γ: 76.47 ± 0.03°
• Cell volume: 3490.9 ± 1.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1065
• Residual factor for significantly intense reflections: 0.0566
• Weighted residual factors for significantly intense reflections: 0.1228
• Weighted residual factors for all reflections included in the refinement: 0.1332
• Goodness-of-fit parameter for all reflections included in the refinement: 0.794
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No