Information card for entry 7060978

Structure parameters

• Formula: C45 H57 Cl Co N2 O2 P3 Si
• Calculated formula: C45 H57 Cl Co N2 O2 P3 Si
• Title of publication: Synthesis and properties of [PCP] pincer silylene cobalt(i) complexes
• Authors of publication: Li, Yonghui; Fan, Qingqing; Yang, Haiquan; Xie, Shangqing; Huang, Wei; Li, Xiaoyan; Sun, Hongjian; Fuhr, Olaf; Fenske, Dieter
• Journal of publication: New Journal of Chemistry
• Year of publication: 2021
• Journal volume: 45
• Journal issue: 42
• Pages of publication: 19950 - 19956
• a: 10.1744 ± 0.0003 Å
• b: 9.3902 ± 0.0002 Å
• c: 46.7097 ± 0.0014 Å
• α: 90°
• β: 94.478 ± 0.002°
• γ: 90°
• Cell volume: 4449 ± 0.2 ų
• Cell temperature: 150.15 K
• Ambient diffraction temperature: 150.15 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0792
• Residual factor for significantly intense reflections: 0.062
• Weighted residual factors for significantly intense reflections: 0.1556
• Weighted residual factors for all reflections included in the refinement: 0.1648
• Goodness-of-fit parameter for all reflections included in the refinement: 1.081
• Diffraction radiation wavelength: 1.34143 Å
• Diffraction radiation type: GaKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No